A Novel Accelerated Stress Test for a Representative Enhancement of Cathode Degradation in Direct Methanol Fuel Cells
نویسندگان
چکیده
Performance decay of direct methanol fuel cells hinders technology competitiveness. The cathode electrochemical surface area loss is known to be a major reason for performance and it mainly affected by potential dynamics, locally influenced water crossover. To mitigate such phenomenon, novel materials components need developed intensively tested in relevant operating conditions. Thus, the development representative accelerated stress tests crucial reduce necessary testing time assess material stability. In literature, most diffused commonly enhance specific degradation mechanism, each resulting limited representativeness complex combination interaction mechanisms involved during real-life operation. This work proposes test procedure permitting quantifiable predictable acceleration degradation, with goal being real device results obtained 200 h are validated comparing both situ post mortem measurements those performed 1100 operational test, demonstrating an factor equal 6.25x confirming consistent degradation.
منابع مشابه
Enhancing the methanol tolerance of platinum nanoparticles for the cathode reaction of direct methanol fuel cells through a geometric design
Mastery over the structure of nanoparticles might be an effective way to enhance their performance for a given application. Herein we demonstrate the design of cage-bell nanostructures to enhance the methanol tolerance of platinum (Pt) nanoparticles while remaining their catalytic activity for oxygen reduction reaction. This strategy starts with the synthesis of core-shell-shell nanoparticles w...
متن کاملNovel Anode Catalyst for Direct Methanol Fuel Cells
PtRu catalyst is a promising anodic catalyst for direct methanol fuel cells (DMFCs) but the slow reaction kinetics reduce the performance of DMFCs. Therefore, this study attempts to improve the performance of PtRu catalysts by adding nickel (Ni) and iron (Fe). Multiwalled carbon nanotubes (MWCNTs) are used to increase the active area of the catalyst and to improve the catalyst performance. Elec...
متن کاملRecent progress in the development of anode and cathode catalysts for direct methanol fuel cells
nt matter & 2013 0.1016/j.nanoen.2 thor. Tel.: +82 54 . nt_tiw123@yahoo Abstract Continuous growth in global energy demand has sparked concerns about energy security and environmental sustainability. In the past two decades, attempts have been made in the development of innovative energy technologies. The direct methanol fuel cell (DMFC) is among the most promising alternative energy sources fo...
متن کاملNovel synthesis of highly active Pt/C cathode electrocatalyst for direct methanol fuel cell.
A 40 wt% Pt/C cathode electrocatalyst with controlled Pt particle size of approximately 2.9 nm showing better performance than commercial catalyst for direct methanol fuel cell was prepared by a polyol process with water but without using stabilizing agent.
متن کاملTowards neat methanol operation of direct methanol fuel cells: a novel self-assembled proton exchange membrane.
We report here a novel proton exchange membrane with remarkably high methanol-permeation resistivity and excellent proton conductivity enabled by carefully designed self-assembled ionic conductive channels. A direct methanol fuel cell utilizing the membrane performs well with a 20 M methanol solution, very close to the concentration of neat methanol.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Energies
سال: 2023
ISSN: ['1996-1073']
DOI: https://doi.org/10.3390/en16073226